Nadine Chelsea Sutcliffe

 Nadine Chelsea Sutcliffe

Nadine Chelsea Sutcliffe

  • Courses1
  • Reviews1

Biography

University of Toronto St. George Campus - Geology


Resume

  • 2009

    Doctor of Philosophy - PhD

    Thesis title - Strontium stable isotope behaviour accompanying melting and magmatism in the Earth - Moon system\n\nHigh-precision analysis of non-traditional isotopes in high-temperature cosmochemistry.

    Geochemistry and cosmochemistry

    University of Oxford

  • 2005

    MSci

    Awarded the Illing Prize for Outstanding Achievement in Petroleum Geoscience

    Geological and Earth Sciences/Geosciences

    Imperial College London

    1st Class with Honours

  • Trained as a Wikipedia Fellow to write and edit Wikipedia articles to promote women in STEM.\n\nhttps://wikiedu.org/blog/2019/03/06/experimenting-with-wikipedia-as-a-woman-in-stem/\n\nhttps://wikiedu.org/blog/2018/11/08/scientists-to-write-wikipedia-biographies-of-women-in-stem/

    Wiki Education Foundation

    Public Outreach

    Presentation Skills

    Earth Science

    Lecturing

    Isotope Geochemistry

    Hydrogeology

    Manuscript reviewing and editing

    Problem Solving

    Project Management

    Geochemistry

    Scientific Writing

    Data Collection

    Science Outreach

    Team Leadership

    Geochronology

    Research

    Data Analysis

    Science Communication

    Mass Spectrometry

    Nuclear Waste Management

    Improving paleohydrological and diagenetic reconstructions in calcite veins and breccia of a sedimentary basin by combining Δ47 temperature

    δ18Owater and U-Pb age

    Improving paleohydrological and diagenetic reconstructions in calcite veins and breccia of a sedimentary basin by combining Δ47 temperature

    δ18Owater and U-Pb age

    U-Pb ages have been measured on secondary dolomite and silica cements in Cambrian sandstone at the base of an 840 m thick sub-horizontally bedded sedimentary sequence beneath the Bruce nuclear site in southern Ontario to document the history of fluid movement. Results show an average U-Pb age of 320 ± 10 Ma. The initial common Pb end member is slightly but distinctly enriched in 206Pb compared to that in older and younger calcite cements elsewhere within the sedimentary section. Combined with previous hydro-geochemical and fluid inclusion studies on the same rocks

    the age is interpreted to record episodic migration of a saturated hydrothermal brine. Previously dated calcite cement in sub-horizontal fractures about 500 m higher in the stratigraphic section near the base of the Silurian sequence records similar U-Pb ages of 318 ± 10 Ma by LA-ICPMS and 313 ± 1 Ma by ID-TIMS. We suggest that the subhorizontal fractures were generated by slumping that resulted from dissolution of underlying evaporite deposits. These ages overlap with the peak of plutonism in the Alleghanian mountains

    which were being uplifted contemporaneously 500 km to the southeast. Results suggest transport of hydrothermal brine from areas of crustal melting through the deep Cambrian sandstone aquifer while

    at higher crustal levels

    meteoric water was also driven over equally large distances by hydraulic gradients from the Alleghanian mountains.

    Hydrochronology of a proposed deep geological repository for Low and Intermediate nuclear waste in southern Ontario from U-Pb dating of secondary minerals: Response to Alleghanian events

    The relative abundances of resolved 12CH2D2 and 13CH3D and mechanisms controlling isotopic bond ordering in abiotic and biotic methane gases

    A record of fluid flow has been documented within a Paleozoic carbonate platform sequence by U-Pb dating of calcite in veins and vugs from rock core sampled through a shallowly dipping sequence of sedimentary rocks beneath the Bruce nuclear site

    Ontario

    Canada. Secondary calcite from >650 m deep Ordovician carbonate rocks yields a Silurian age of 434 ± 5 Ma possibly related to infiltration of seawater from overlying evaporitic basins as well as hydrothermal solutions that infiltrated from below. In contrast

    near-surface Devonian rocks mostly give vein infill ages over the range 80-100 Ma with evidence for younger infill down to 50 Ma. Vein calcite samples previously dated from surface outcrops of Ordovician carbonate exposed up to 500 km to the east yield similar U-Pb ages. Coincidence of near-surface vein calcite ages indicates widespread vein emplacement synchronous with a change in direction of motion of the North American plate as well as possible erosional unroofing following passage of the region over the Great Meteor hot spot ca. 125 Ma ago. Deeper carbonate formations have remained apparently impermeable to post-Paleozoic disturbance despite these perturbations.

    Hydrochronology of a proposed deep geological repository for low and Intermediate level nuclear waste in southern Ontario from U-Pb dating of secondary minerals: Response to Silurian and Cretaceous events

    The Jurassic clay-rich aquitard sequence underlying the Swiss Molasse Basin is locally penetrated by unusually frequent veins consisting of calcite ± celestite

    in particular in the Schlattingen-1 and Oftringen drill cores. The veins are linked to extensional brittle structures

    with shear senses ranging between dip-slip and strike-slip. Deformation triggered transient and localised events of fluid flow within the aquitard followed by sealing of the structures by the vein minerals. Vein calcite was dated by LA-ICP-MS analysis using the U/Pb method. While this was a demanding undertaking

    given the low U and high common Pb contents of calcite

    9 significant ages could be obtained. Two groups of ages can be distinguished

    namely 31–39 and 11–18 Ma. Both age groups are consistent with the known regional tectonic evolution. The older age group corresponds to the main phase of rifting in the Upper Rhine Graben

    a major crustal discontinuity

    whose effects were not limited to the graben proper but affected large parts of the Molasse Basin.

    Veins in clay-rich aquitards as records of deformation and fluid-flow events in northern Switzerland

    Tracing ancient hydrogeological fracture network age and compartmentalisation using noble gases

    Precambrian Shield rocks host the oldest fracture fluids on Earth

    with residence times up to a billion years or more. Water-rock reactions in these fracture systems over geological time have produced highly saline fluids

    which can contain mM concentrations of H2. Mixing of these ancient Precambrian fluids with meteoric or palaeometeoric water can occur through tectonic fracturing

    providing microbial inocula and redox couples to fuel blooms of subsurface growth. Here

    we present geochemical and microbiological data from a series of borehole fluids of varying ionic strength (0.6 M to 6.4 M) from Thompson Mine (Manitoba) within the Canadian Precambrian Shield. Thermodynamic calculations demonstrate sufficient energy for H2-based catabolic reactions across the entire range of ionic strengths during mixing of high ionic strength fracture fluids with meteoric water

    although microbial H2 consumption and cultivable H2-utilizing microbes were only detected in fluids of ≤ 1.9 M ionic strength. This pattern of microbial H2 utilization can be explained by the greater potential bioenergetic cost of organic osmolyte synthesis at increasing ionic strengths. We propose that further research into the bioenergetics of osmolyte regulation in halophiles is warranted to better constrain the habitability zones of hydrogenotrophic ecosystems in both the terrestrial subsurface

    including potential future radioactive waste disposal sites

    and other planetary body crustal environments

    including Mars.

    Bioenergetic Constraints on Microbial Hydrogen Utilization in Precambrian Deep Crustal Fracture Fluids

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification

    the abundance of its multiply-substituted \"clumped\" isotopologues

    e.g.

    (13)CH3D

    has recently emerged as a proxy for determining methane-formation temperatures; however

    the impact of biological processes on methane's clumped isotopologue signature is poorly constrained. We show that methanogenesis proceeding at relatively high rates in cattle

    surface environments

    and laboratory cultures exerts kinetic control on (13)CH3D abundances and results in anomalously elevated formation temperature estimates. We demonstrate quantitatively that H2 availability accounts for this effect. Clumped methane thermometry can therefore provide constraints on the generation of methane in diverse settings

    including continental serpentinization sites and ancient

    deep groundwaters. Copyright © 2015

    American Association for the Advancement of Science.

    Methane cycling. Nonequilibrium clumped isotope signals in microbial methane

    Chelsea

    Sutcliffe

    Natural Sciences and Engineering Research Council of Canada (NSERC)

    University of Toronto

    Jack Satterly Geochronology Laboratory

    I use high precision U-Pb geochronology to age date fracture minerals and investigate the hydrogeology of proposed sites for the safe disposal of radioactive waste

    partnered with the Nuclear Waste Management Organization (NWMO). \nAge dating zircons for exploration geology with the Ontario Geological Survey

    Quebec Survey

    and multiple academic partners and institutions.

    Postdoctoral Research Fellow

    University of Toronto

    Postdoctoral Fellow of the Canadian Astrobiology Training Program (CATP)

    first Canadian cross-disciplinary

    multi-institutional undergraduate

    graduate and postdoctoral training program in Astrobiology. NSERC CREATE.

    Natural Sciences and Engineering Research Council of Canada (NSERC)

    University of Toronto

    Toronto

    - Design

    develop and execute new geochemical research projects focused on LA-ICP-MS and TIMS analyses for 1) fracture infill studies for site investigations to assess the suitability for hosting a deep geological repository for intermediate-level nuclear waste

    2) geochronological analyses of the Canadian Shield

    and 3) mineral investigation. \n- Interpret raw geoscientific data for publication in peer-reviewed journals and present research findings at conferences and meetings.

    Research Associate

    Stable Isotope Laboratory

    Investigated the geochemistry of ancient saline fracture fluids in the Precambrian Shield. Used stable C

    H

    and O isotopes and gas source mass spectrometry to understand the provenance of crustal fluids.\nResearch highlighted in the New Scientist

    BBC

    CBC

    and published in Science.

    Postdoctoral Research Fellow

    University of Toronto

    Create and implement course syllabi and assessments for both undergraduate and graduate level science courses. \nDesign and deliver lectures and seminars to undergraduates and graduates. \nResponsible for the improvement of courses based on student evaluations and feedback.

    University of Toronto

    Wiki Education

    Selected to participate in a course to train scholars as Wikipedia Fellows with the skills to write and edit Wikipedia articles to promote women in STEM.\n\nhttps://wikiedu.org/blog/2018/11/08/scientists-to-write-wikipedia-biographies-of-women-in-stem/

    Wikipedia Fellow Volunteer

    English

    Spanish

    Illing Prize

    Outstanding achievement

    awarded upon graduating.

    Imperial College London

PMUHF 1991

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